/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

1 article(s) from Manteau, Baptiste

Trifluoromethyl ethers – synthesis and properties of an unusual substituent

Frédéric R. Leroux,
Baptiste Manteau,
Jean-Pierre Vors and
Sergiy Pazenok

Beilstein J. Org. Chem. 2008, 4, No. 13, doi:10.3762/bjoc.4.13

PDF

Graphical Abstract

Figure 1: OCF₃-bearing pesticides.

Jump to Figure 1

Scheme 1: Preparation of trifluoromethyl ethers via a chlorination/fluorination sequence.

Jump to Scheme 1

Scheme 2: Preparation of trifluoromethyl ethers via an in situ chlorination/fluorination sequence.

Jump to Scheme 2

Scheme 3: Preparation of trifluoromethyl ethers via chlorothionoformates.

Jump to Scheme 3

Scheme 4: Preparation of trifluoromethyl ethers via fluoroformates.

Jump to Scheme 4

Scheme 5: Oxidative desulfurization-fluorination toward trifluoromethyl ethers.

Jump to Scheme 5

Scheme 6: Mechanism of the oxidative desulfurization-fluorination.

Jump to Scheme 6

Scheme 7: Umemoto's O-(trifluoromethyl)dibenzofuranium salts 4 as CF₃-transfer agents.

Jump to Scheme 7

Scheme 8: Togni's approach using hypervalent iodine compounds as CF₃-transfer agents.

Jump to Scheme 8

Scheme 9: TAS OCF₃ as a nucleophilic OCF₃-transfer agent.

Jump to Scheme 9

Figure 2: Mesomeric structures of the OCF₃-group.

Jump to Figure 2

Figure 3: Structures of 6 and 7.

Jump to Figure 3

Figure 4: Conformational preference of the trifluoromethoxy group on aryl rings.

Jump to Figure 4

Scheme 10: Nitration of trifluoromethoxy benzene.

Jump to Scheme 10

Scheme 11: Synthesis and Nitration of N-Acetyl-(trifluoromethoxy)anilines.

Jump to Scheme 11

Scheme 12: Bromine/lithium exchange of bromo(trifluoromethoxy)benzenes.

Jump to Scheme 12

Scheme 13: Metalation of (trifluoromethoxy)benzene.

Jump to Scheme 13

Scheme 14: Metalation of (trifluoromethoxy)naphthalenes.

Jump to Scheme 14

Scheme 15: Competition between -CF₃- and -OCF₃ in Metalation reactions.

Jump to Scheme 15

Scheme 16: Competition between -F- and -OCF₃ in Metalation reactions.

Jump to Scheme 16

Scheme 17: Metalation of trifluoromethoxyanisoles.

Jump to Scheme 17

Figure 5: Direction of π-polarization depending on the substituent as described by Schlosser et al. [57].

Jump to Figure 5

Scheme 18: Metalation of Bromo(trifluoromethoxy)benzenes.

Jump to Scheme 18

Scheme 19: Aryne formation from bromo(trifluoromethoxy)phenyllithiums and subsequent Diels-Alder cycloaddition...

Jump to Scheme 19

Scheme 20: Metalation of (trifluoromethoxy)anilines.

Jump to Scheme 20

Album

Review

Published 29 Apr 2008

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum